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Organic & Biomolecular Chemistry

A direct oxidative esterification of aldehydes with alcohols mediated by photochemical C–H bromination†

Haru Ando,a   Sakura Kodaki,a   Hiroyoshi Takamura, ORCID logo a   Isao Kadota*a  and  Kenta Tanaka ORCID logo *b  

* Corresponding authors

a Department of Chemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushima-Naka, Kitaku, Okayama 700-8530, Japan
E-mail: kadota-i@okayama-u.ac.jp

b Research Institute for Interdisciplinary Science, Okayama University, 3-1-1 Tsushima-Naka, Kitaku, Okayama 700-8530, Japan
E-mail: ktanaka@okayama-u.ac.jp

Abstract

The photochemical direct esterification of aldehydes with alcohols via in situ-generated acyl-bromides presented in this report is an attractive complementary addition to hitherto reported methods, as these are usually carried out in a two-step, one-pot procedure in order to avoid side reactions such as the oxidation of alcohols by halogen sources.

Graphical abstract: A direct oxidative esterification of aldehydes with alcohols mediated by photochemical C–H bromination

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Article information

DOI
https://doi.org/10.1039/D4OB01237B
Article type
Communication
Submitted
27 Jul 2024
Accepted
29 Aug 2024
First published
30 Aug 2024
This article is Open Access
Creative Commons BY-NC license

Org. Biomol. Chem., 2024, Advance Article

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A direct oxidative esterification of aldehydes with alcohols mediated by photochemical C–H bromination

H. Ando, S. Kodaki, H. Takamura, I. Kadota and K. Tanaka, Org. Biomol. Chem., 2024, Advance Article , DOI: 10.1039/D4OB01237B

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