SCHEDULED MAINTENANCE
Herein, we report a diastereoselective dearomative bifunctionalization strategy of isoquinolinium salts to access bridged tetrahydroisoquinolines. The strategy relies on the strategic use of allenes and amines as reaction partners to in situ generate binucleophilic species for subsequent dearomatization.
J. Pei, T. Tang, J. Zhang, Y. Qin, P. Cheng and Q. Wang, New J. Chem., 2024, Accepted Manuscript , DOI: 10.1039/D4NJ02968B
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