SCHEDULED MAINTENANCE
The synthesis of potassio-1H-silolides and -germolides substituted with an aminidate-stabilized silylene is reported. Both anions undergo a thermal rearrangement to the 2H-isomer yielding cyclic sila- and germavinyl anions. The reaction is driven by complex formation with metal ions.
T. Müller, C. Liu and M. Schmidtmann, Chem. Commun., 2024, Accepted Manuscript , DOI: 10.1039/D4CC03984J
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