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DOI: 10.1039/D4QI01292E (Research Article) Inorg. Chem. Front., 2024, 11, 4647-4653

Switchable coordination bonds in 3D cyano-bridged perovskite ferroelastics: achieving the largest leap of symmetry breaking and enhanced dielectric switching performance†

Sheng-Qian Hu , Meng-Zhen Li , Zhao-Hong Chen , Jun-Si Zhou , Luan-Ying Ji , Yong Ai and Xiao-Gang Chen *
Ordered Matter Science Research Center, Nanchang University, 330031, P. R. China. E-mail: chenxg@ncu.edu.cn

Received 22nd May 2024 , Accepted 15th June 2024

First published on 17th June 2024

Abstract

Three-dimensional (3D) cyano-bridged perovskites, with a larger framework than their metal–halide counterparts, have shown great promise in the design of molecular ferroelastic, ferroelectric, and even multiferroic materials. However, the relatively weak interaction between the organic cations and the rigid cyano-bridged framework usually makes them exhibit a low phase transition temperature (Tc) and inadequate performance. In this study, we used the parent compounds [C3H6NH2]2[MFe(CN)6] (C3H6NH2 = azetidinium, M = K, Rb or Cs) as starting points to design a variety of 3D cyano-bridged perovskite ferroelastic materials [C3H5FNH2]2[MFe(CN)6] (C3H5FNH2 = 3-fluoroazetidinium) through the H/F substitution strategy. Notably, in comparison with [C3H6NH2]2[MFe(CN)6], the strongest electronegative fluorine atom of [C3H5FNH2]+ cations forms a C–F–M coordination bond with alkali metal ions, which greatly enhances the interaction between the cation and the framework, thus increasing Tc. The transition from order to disorder in [C3H5FNH2]+ cations, coupled with the generation/breakage of switchable C–F–M coordination bonds, synergistically results in the largest leap of symmetry breaking with an Aizu notation of m[3 with combining macron]mF[1 with combining macron] and is responsible for significantly enhancing the dielectric switching performance. This study offers an effective approach for discovering novel molecular ferroelastics with excellent switchable physical properties.

Introduction

Ferroelastic materials are crucial for various potential applications including mechanical switches, shape memory devices, energy conversion systems, information processing technologies, solar cells, and multifunctional superelasticity.1–8 Organic–inorganic hybrid perovskites (OIHPs), in comparison with their inorganic counterparts, have garnered increasing interest in recent years due to their environmentally friendly nature, ease of processing, mechanical flexibility, affordability, and biocompatibility.9–26 Their unique structures, where the inorganic component guarantees stability and fascinating electro-optical properties while the organic part provides structural flexibility and variability, offer great potential for constructing and optimizing multifunctional ferroelastic materials.27–34 Among these, three-dimensional (3D) cyano-bridged perovskites have attracted considerable attention, primarily because many cyanide compounds exhibit an intriguing dielectric property switchability triggered by structural phase transitions.35–38 In 3D cyano-bridged perovskites, various metal ions can be linked by the cyanide ions to form the striking double perovskite structure, A2[B′B′′(CN)6] (A = monovalent cation, B′(I) = monovalent metals, such as K+, Rb+, and Cs+, and B′′(III) = trivalent metals, such as Fe3+ and Co3+). Incorporating cationic A guests into the host cages formed by B′−NC−B′′ results in the assembly of a 3D hole structure, making it a highly promising class of switchable molecular dielectrics.39–42 The mechanisms of dielectric switching in these cyano-bridged OIHP ferroelastics typically arise from the conventional order–disorder transition of the A-site guests.43–45 In this transition, the ordered state corresponds to a low dielectric constant (referred to as ‘switching-off’), whereas the disordered state corresponds to an activated high dielectric constant (referred to as ‘switching-on’). However, the larger B′–NC–B′′ framework results in a weaker confinement effect for the A-site cations within the cage, leading to a lower Tc and unspectacular symmetry breaking, which makes it difficult to achieve large dielectric switching responses and hinders its application in practical electronic devices.

To address this challenge, Xu et al.46 pioneered the introduction of switchable coordination bonds into this 3D cyano-bridged perovskite system. The generation/breakage of the N–O–K coordination bonds between [(CH3)3NOH]+ cations and the [KFe(CN)6]2− framework led to a significant symmetry breaking with transitioning from the high-temperature cubic non-polar Fm[3 with combining macron]m space group (No. 225) to the low-temperature monoclinic polar Cc space group (No. 9) in [(CH3)3NOH]2[KFe(CN)6], thereby yielding a 3D perovskite ferroelectric with both high Tc up to 402 K and excellent multipolar axis properties. Similar properties were also reported by Rok et al. in their Co-based analogs.47 Thus, mastering the structural phase transition mechanism and manipulating the crystal symmetry are essential for obtaining high-performance ferroic materials.48 However, to date, research on switchable coordination bond ferroelastic materials remains scarce.

Hydrogen/fluorine (H/F) substitution, involving the replacement of an H atom with an F atom in organic cations, minimally disrupts the crystal structure while significantly increasing Tc and has been widely used to construct ferroelectric and ferroelastic materials.49–52 For instance, employing a fluorine substitution strategy, ferroelectrics like (4-fluoro-1-azabicyclo[2.2.1]heptane)CdCl3, (R) and (S)-3-(fluoropyrrolidinium)MnCl3, and (R) and (S)-(N,N-dimethyl-3-fluoropyrrolidinium)iodide exhibit enhanced Tc, demonstrating the comparable or even superior performance of H/F substitution compared to the isotope effect.53–55 In contrast to the aforementioned cases, we recently discovered that the strong electronegative F atom in the organic cation can form a coordination bond with K+ ions from the [KFe(CN)6]2− framework, which can reduce the symmetry of the parent compound from the tetragonal I4/m space group (No. 87) to the monoclinic C2/c space group (No. 9).48 This inspired the development of high-performance switchable coordination bond ferroelastic materials.

In this study, we successfully devised and synthesized a series of 3D cyano-bridged perovskite ferroelastics, denoted as [C3H5FNH2]2[MFe(CN)6], which we named FAZT-K, FAZT-Rb, and FAZT-Cs when M = K, Rb, and Cs, respectively. This was achieved via H/F substitution starting from the parent compounds [C3H6NH2]2[MFe(CN)6], referred to as AZT-K, AZT-Rb, and AZT-Cs, respectively (Scheme 1). Notably, the establishment of switchable C–F–M coordination bonds between the [C3H5FNH2]+ cations and the [MFe(CN)6]2− framework not only played a significant role in enhancing Tc, but also led to the largest leap of symmetry breaking with the Aizu notation of m[3 with combining macron]mF[1 with combining macron] among the 3D cyano-bridged perovskites (Fig. S1 and Table S1, ESI†). Among them, FAZT-Rb exhibits favorable dielectric switching performance with ΔTc as high as 132 K, and a ratio of dielectric switching of up to 5. To our knowledge, this method of achieving the effect of killing three birds with one stone, that is, simultaneously increasing Tc, improving the switchable dielectric response, and intensifying the symmetry breaking, is unprecedented in the design of molecular ferroelastic materials.


image file: d4qi01292e-s1.tif
Scheme 1 Schematic strategy of H/F substitution for designing compounds FAZT-K, FAZT-Rb, and FAZT-Cs.

Results and discussion

Differential scanning calorimetry (DSC)

All compounds were obtained by evaporating the aqueous solution at a slow rate, resulting in reddish-brown block-like crystals (Fig. S2, ESI†), demonstrating excellent thermal stability up to 500 K, except for FAZT-Cs as indicated by TGA analyses (Fig. S3, ESI†). Powder X-ray diffraction measurement at room temperature confirmed their good phase purity (Fig. S4, ESI†). Differential scanning calorimetry (DSC) measurements conducted at a rate of 20 K min−1 revealed the phase transitions of FAZT-K, FAZT-Rb, and FAZT-Cs at around 295 K, 350 K, 379 K (Tc1 of FAZT-Cs), and 394 K (Tc2 of FAZT-Cs), respectively (Fig. 1a). The Tc of [C3H5FNH2]2[MFe(CN)6] was observed to increase with the enlargement of the radius of the M component (rM). Despite FAZT-Cs exhibiting the highest Tc, its stability was found to be poor, leading us to focus on studying FAZT-Rb in detail. Upon heating and cooling, FAZT-Rb and AZT-Rb experienced reversible phase transitions at 350 K and 218 K, respectively (Fig. 1b). The sharp peaks and large thermal hysteresis of 16 K in FAZT-Rb and 24 K in AZT-Rb suggest a distinctive feature of the first-order phase transition. Moreover, a significant enhancement of 132 K in the Tc of FAZT-Rb compared to AZT-Rb indicates that H/F substitution on AZT-Rb effectively improves Tc. Similarly, after fluorination, the Tc of FAZT-K increased from 193 K (compared to AZEFe56) to 295 K (Fig. S5, ESI†), the Tc of FAZT-Cs increased from 300 K to 379 K (Tc1 of FAZT-Cs), and 394 K (Tc2 of FAZT-Cs) (Fig. S6, ESI†), providing powerful evidence for the role played by H/F substitution. For convenience, we label the phases above 350 K for FAZT-Rb and 218 K for AZT-Rb as the high-temperature phase (HTP), and the phases below 334 and 194 K, as the low-temperature phase (LTP). The same applies to FAZT-K, AZT-K, FAZT-Cs, and AZT-Cs, but for FAZT-Cs, we introduce the intermediate-temperature phase (ITP) to describe the phase between Tc1 and Tc2.
image file: d4qi01292e-f1.tif
Fig. 1 (a) DSC curves upon heating for FAZT-K, FAZT-Rb, and FAZT-Cs and (b) DSC curves of FAZT-Rb and AZT-Rb.

Dielectric properties

The temperature-dependent dielectric constants were measured for all compounds. As depicted in Fig. 2a, 2b, and S7 (ESI),† FAZT-K, AZT-K,56 FAZT-Rb, AZT-Rb, and AZT-Cs all display step-like dielectric anomalies in the real part (ε′) of the dielectric constant around Tc in both heating and cooling modes, indicating reversible phase transitions consistent with the DSC results. Fig. S7c (ESI)† reveals dielectric transitions around Tc2 for FAZT-Cs, exhibiting peak-like anomaly in the heating process and damped step-like anomaly during the cooling process, suggesting its thermal instability. For instance, in LTP, the ε′ of FAZT-Rb remains stable at about 6.6, while for AZT-Rb, it is approximately 5, indicating the low dielectric state. As the temperature continues to increase towards Tc, the values of ε′ of FAZT-Rb and AZT-Rb dramatically increase to 33 and 20, respectively, within a narrow temperature region. In the HTP, their ε′ remains almost unchanged, corresponding to the high dielectric state. Compared to AZT-Rb, which exhibits a switching ratio of 4, FAZT-Rb shows an improvement after fluoridation with a ratio between high and low dielectric states of 5. As for FAZT-Cs, the ε′ values are 27.5 and 9.15 at 393 and 360 K, respectively, in the heating process, and the ratio is 3 (Fig. S7c, ESI†).
image file: d4qi01292e-f2.tif
Fig. 2 Temperature-dependent dielectric constants of FAZT-Rb (a) and AZT-Rb (b); reversible dielectric switching (ON and OFF) of ε′ between the HTP and LTP measured for FAZT-Rb (c) and AZT-Rb (d) at 1 MHz.

As illustrated in Fig. 2c, 2d, and S8 (ESI),† for FAZT-K, AZT-K, FAZT-Rb, AZT-Rb, and AZT-Cs, ε′ switching is stable and remains constant after at least five cycles. In each cycle, the low dielectric state represents “switch-off”, while the high dielectric state signifies “switch-on”. Their ε′ undergo reciprocal and rapid changes between the low dielectric state and the high dielectric state as the temperature repeatedly crosses above or below Tc. The repetition of ON/OFF cycles suggests potential electronic applications for the compounds we studied.

Structural analyses

FAZT-K, FAZT-Rb, and FAZT-Cs were designed through H/F substitution on the azetidine cations based on AZT-K, AZT-Rb, and AZT-Cs, respectively. Their structural analysis was conducted using variable temperature single-crystal X-ray diffraction (XRD). Taking FAZT-Rb and AZT-Rb as examples, in the LTP, the asymmetric units of both contain two organic cations, one [Fe(CN)6]3− anion, and one Rb+ (Fig. 3a and b). Both compounds exhibit double perovskite cage structures where each Fe3+ ion connects six Rb+ ions via CN− linkers (Fe–C[triple bond, length as m-dash]N–Rb), forming the 3D metal–organic framework as hosts and cations are located in the cages as guests (Fig. 3c–h). The key difference is that FAZT-Rb forms switchable C–F–Rb coordination bonds after fluorination, reducing the symmetry from the monoclinic P21/c space group to the triclinic P[1 with combining macron] space group (Table S2, ESI†). In the LTP of FAZT-Rb (300 K), the perovskite cavities accommodate ordered 3-fluoroazetidine cations, which are connected to the neighboring Rb+ ions via C–F–Rb coordination bonds (Fig. 3e and g). The movements of guest molecules are inhibited by the C–F–Rb coordination bonds with distances of 3.147(10) Å, accompanied by the distortion of Fe–CN–Rb bridges and slight deformation of the anionic framework (Tables S3 and S4, ESI†).
image file: d4qi01292e-f3.tif
Fig. 3 Crystal structures of FAZT-Rb and AZT-Rb. The asymmetric unit in the LTP of AZT-Rb (a) and FAZT-Rb (b) is drawn as displacement ellipsoids with 50% probability. The basic unit of the framework in the LTP and HTP of AZT-Rb (c), (d) and FAZT-Rb (e), (f). Perspective view of the packing structure of FAZT-Rb in the LTP (g) and HTP (h). The hydrogen atoms in the HTP are omitted for clarity.

In the HTP (373 K), FAZT-Rb crystallizes in the cubic space group Fm[3 with combining macron]m, with the guest molecules exhibiting a 24-fold disorder (Fig. 3f and h). The bond lengths of the metal–organic cage have identical values, resulting in an ideal octahedral geometry due to the high symmetry (Tables S3 and S4, ESI†). During the heating process, the C–F–Rb coordination bonds connecting the main framework and 3-fluoroazetidine cations are broken and the nitrogen atoms of the inorganic framework become a 4-fold disorder. Additionally, the cell volume at 300 K is smaller compared to that of the HTP. Thus, the primary structural difference between the HTP and LTP lies in the distinct motion modes of the guest molecules, as well as the slight change in the framework structure of the [Rb4Fe4(CN)12] cage. Furthermore, the order–disorder transition of 3-fluoroazetidine cations and the generation/cleavage of switchable C–F–Rb coordination bonds drive the structural phase transition at 350 K, resulting in the largest leap of symmetry breaking from a cubic paraelastic phase (Fm[3 with combining macron]m) to a triclinic ferroelastic phase (P[1 with combining macron]). Moreover, the cations of the AZT-Rb are highly ordered in the LTP and become dynamically disordered in the HTP (Fig. 3c and d), which is responsible for the reversible ferroelastic transition with an Aizu notation of m[3 with combining macron]mF2/m. Significantly, as both FAZT-Rb and AZT-Rb underwent order–disorder transition, the rotating motions of the organic cations generate a potential energy barrier, which may be heightened by H/F substitution, thereby enhancing Tc. As shown in Fig. S9 and S10 (ESI),† FAZT-K and FAZT-Cs exhibit a similar disordered model to FAZT-Rb in the HTP, crystallizing in the P[1 with combining macron] space group in the LTP, and experiencing the same ferroelastic phase transition as FAZT-Rb with an Aizu notation of m[3 with combining macron]mF[1 with combining macron]. Similarly, the states of AZT-K56 and AZT-Cs resemble AZT-Rb in the HTP, but in the LTP AZT-K has a different space group from AZT-Rb, which is P42/m, while AZT-Cs shares the same space group P21/c as AZT-Rb. Notably, the azetidine cations in the LTP of AZT-K as well as the fluorine atoms in the LTP of FAZT-Cs are disordered. In the ITP, FAZT-Cs crystallizes in the C2/c space group, where partial nitrogen atoms of the host framework are disordered. The geometrical parameters of FAZT-K, AZT-K, FAZT-Cs, and AZT-Cs are summarized in Tables S5–S10 (ESI).†

Ferroelastic domains

The m[3 with combining macron]mF[1 with combining macron] and the m[3 with combining macron]mF2/m transitions may lead to 24 and 12 possible orientation states, respectively, which exhibit characteristics of ferroelastics.35 To validate the ferroelasticity of FAZT-K, FAZT-Rb, and AZT-Rb, polarized light microscopy was employed to observe the evolution of ferroelastic domains. Ferroelastic domains with different orientations manifest distinct patterns of light and dark under perpendicular polarized light due to their differing birefringence properties. As illustrated in Fig. 4, the crystal samples presented clearly stable interlaced stripe-like ferroelastic domains in the ferroelastic phase (FP) before reaching the Tc, including 90° ferroelastic domains. When the temperature rose above Tc at 372 K, the crystal gradually transitioned into the paraelastic phase (PP), and the ferroelastic domain patterns disappeared entirely, displaying uniform extinction properties owing to the high symmetry of the cubic phase. Subsequently, during the cooling process below Tc, the striped domain patterns reemerged with birefringence. The evolution of ferroelastic domains clearly demonstrates the favorable switchability of ferroelastic phase transitions. Similar ferroelastic phase transitions of AZT-Rb and FAZT-K were also observed, as shown in Fig. S11 and S12 (ESI).†
image file: d4qi01292e-f4.tif
Fig. 4 Evolution of ferroelastic domains for FAZT-Rb during the heating process ((a)–(c)) and the cooling process ((d)–(f)).

Conclusions

In conclusion, we have successfully synthesized a series of 3D cyano-bridged perovskite ferroelastics [C3H5FNH2]2[MFe(CN)6] (M = K (FAZT-K), Rb (FAZT-Rb), and Cs (FAZT-Cs)), achieving a significant enhancement of Tc. This accomplishment showcases an innovative molecular design approach utilizing a fluorine substitution strategy. FAZT-K, FAZT-Rb, and FAZT-Cs underwent structural phase transitions at around 295 K, 350 K, 379 K (Tc1 of FAZT-Cs), and 394 K (Tc2 of FAZT-Cs), respectively, indicating an increase in Tc with the growing radius of the M component, rM. Among them, FAZT-Rb performs the best in Tc enhancement and dielectric switching performance, with C–F–M coordination bonds playing a pivotal role. Compared to the parent compound AZT-Rb, the introduction of C–F–Rb coordination bonds in FAZT-Rb, along with disorder–order motions of [C3H5FNH2]+ cations, facilitates the largest leap of symmetry breaking in 3D cyano-bridged perovskite ferroelastics, leading to the most violent structural phase transition with an Aizu notation of m[3 with combining macron]mF[1 with combining macron]. This study serves as a compelling demonstration of the effectiveness of H/F substitution as a strategy to manipulate Tc and expedite bond-switching phase transitions. It holds promise for the development of new ferroic materials with desirable switchable physical properties at the molecular level.

Data availability

The data supporting this study's findings are available from the corresponding author (Xiao-Gang Chen, e-mail: chenxg@ncu.edu.cn).

Author contributions

S.-Q. H. conceived the study and wrote the manuscript. M.-Z. L. carried out thermal and electrical experiments. J.-S. Zhou, L.-Y. Ji and Y. A. performed the general characterization studies. X.-G. Chen carried out X-ray characterization and guided this work.

Conflicts of interest

There are no conflicts to declare.

Acknowledgements

This work was supported by the National Natural Science Foundation of China (22201120).

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Footnote

† Electronic supplementary information (ESI) available: Fig. S1–S12 and Tables S1–S10. CCDC 2352607–2352619. For ESI and crystallographic data in CIF or other electronic format see DOI: https://doi.org/10.1039/d4qi01292e
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